• 文献标题:   Rapid synthesis of free-standing MoO3/Graphene films by the microwave hydrothermal method as cathode for bendable lithium batteries
  • 文献类型:   Article
  • 作  者:   NOEROCHIM L, WANG JZ, WEXLER D, CHAO Z, LIU HK
  • 作者关键词:   microwave, hydrothermal, freestanding film, moo3 nanobelt, graphene, cathode
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Univ Wollongong
  • 被引频次:   84
  • DOI:   10.1016/j.jpowsour.2012.11.113
  • 出版年:   2013

▎ 摘  要

Highly flexible, binder-free, MoO3 nanobelt/graphene film electrode is prepared by a two-step microwave hydrothermal method. Graphene is first prepared by an ultra-fast microwave hydrothermal method and then mixed with MoO3 solution to synthesize the MoO3 nanobelt/graphene composite, which exhibits the combination of stacked graphene sheets and uniform MoO3 nanobelts with widths of 200-500 nm and lengths of 5-10 mu m. The charge-discharge measurements show that the as-synthesized MoO3/graphene hybrid materials demonstrate excellent rate capability, large capacity, and good cycling stability compared to the pure MoO3 film. An initial discharge capacity of 291 mAh g(-1) can be obtained at 100 mA g(-1), with a capacity of 172 mAh g(-1) retained after 100 cycles. The results show that the MoO3/graphene designed in this study can be used as a free-standing cathode material in rechargeable bendable Lithium batteries. (c) 2012 Elsevier B.V. All rights reserved.