• 文献标题:   Treated Screen Printed Electrodes Based on Electrochemically Reduced Graphene Nanoribbons for the Sensitive Voltammetric Determination of Dopamine in the Presence of Uric Acid
  • 文献类型:   Article
  • 作  者:   MOHAMMADI S, TAHER MA, BEITOLLAHI H
  • 作者关键词:   electrochemically reduced graphene nanoribbon, electrochemical sensor, dopamine, screen printed electrode, uric acid
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Shahid Bahonar Univ Kerman
  • 被引频次:   1
  • DOI:   10.1002/elan.201900767 EA JUN 2020
  • 出版年:   2020

▎ 摘  要

In this research, the graphene oxide nanoribbons (GONRs) were substantially synthesized by the oxidative longitudinal unzipping of the multi-walled carbon nanotubes (MWCNTs). Then, a direct electrochemical technique was employed for reducing GONRs adsorbed on the screen printed carbon electrode (SPCE). Electrochemical reduction effectively eliminated the oxygen-containing groups in the GONRs and produced the electrochemically reduced graphene nanoribbons (ERGNRs). Field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD) were employed to characterize the materials. The modified SPCE with ERGNRs (ERGNRs/SPCE) displayed acceptable electrocatalytic characteristics towards the oxidation of dopamine (DA) and uric acid (UA) and applied to the simultaneous determination of these two analytes. ERGNRs/SPCE has a peak potential difference of 245 mV between DA and UA. The anodic peak currents of DA and UA were linear within the concentration ranges between 0.5 and 300.0 mu M and 1.0 to 400.0 mu M in phosphate buffer (pH=7.0) respectively. The detection limit of the technique for DA is 0.15 mu M (S/N=3) and for UA is 0.3 mu M (S/N=3). The proposed approach has been applied to the determination of DA and UA in real samples and generated acceptable outputs.