• 文献标题:   ZnWO4 nanocrystals/reduced graphene oxide hybrids: Synthesis and their application for Li ion batteries
  • 文献类型:   Article
  • 作  者:   WANG X, LI BL, LIU DP, XIONG HM
  • 作者关键词:   znwo4, graphene, hybrid, liion battery, anode
  • 出版物名称:   SCIENCE CHINACHEMISTRY
  • ISSN:   1674-7291 EI 1869-1870
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   17
  • DOI:   10.1007/s11426-013-4983-9
  • 出版年:   2014

▎ 摘  要

ZnWO4, as an environment-friendly and economic material, has the potential for Li ion batteries (LIB) application. In this paper, a facile method has been developed to synthesize ZnWO4 supported on the reduced graphene oxide (RGO) to improve its LIB performance. The cuboid-like ZnWO4 nanocrystals are prepared by directly adding Na2WO4 powders into the graphene oxide/Zn aqueous solution followed by a hydrothermal treatment. The high-resolution TEM, XRD and XPS characterizations were employed to demonstrate structural information of the as-prepared ZnWO4/RGO hybrids carefully. Besides, we also discussed the LIB properties of the hybrids based on the detailed galvanostatic charge-discharge cycling tests. As a result, the specific capacity of the as-prepared ZnWO4/RGO hybrids reached more than 477.3 mA h g(-1) after 40 cycles at a current density of 100 mA g(-1) (only less than 159 mA g(-1) for bare ZnWO4). During the whole cyclic process, the coulombic efficiency steadily kept the values higher than 90%.