• 文献标题:   Oxygen-containing Functional Groups Enhancing Electrochemical Performance of Porous Reduced Graphene Oxide Cathode in Lithium Ion Batteries
  • 文献类型:   Article
  • 作  者:   XIONG DB, LI XF, SHAN H, ZHAO Y, DONG L, XU H, ZHANG XF, LI DJ, SUN XL
  • 作者关键词:   thermal exfoliation, graphene, oxygencontaining functional group, lithium ion batterie, cathode material
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Tianjin Normal Univ
  • 被引频次:   49
  • DOI:   10.1016/j.electacta.2015.06.041
  • 出版年:   2015

▎ 摘  要

Exploring high performance and environment-friendly electrode materials is highly desirable for the sustainable Li-ion batteries (LIBs) system. In this study, a facile approach of the modified Hummers' method combining with special thermal reduction was proposed to synthesize nanostructured reduced graphene oxide (RGO) with abundant oxygen-containing functional groups. The resultant RGO showed high specific capacity and excellent cyclability as cathode materials for LIBs. The specific capacity of about 220 mAh g(-1) at a current density of 50 mA g(-1) was achieved after 100 cycles. More importantly, it was demonstrated that the capacity increased with the increase of the amount of oxygen functional groups, highlighting the significant effects of oxygen-containing functional groups of RGO on high lithium storage performance. (C) 2015 Elsevier Ltd. All rights reserved.