• 文献标题:   Rational design of high-rate lithium zinc titanate anode electrode by modifying Cu current collector with graphene and Au nanoparticles
  • 文献类型:   Article
  • 作  者:   LI XX, WANG LJ, LI CF, CHEN BK, ZHAO Q, ZHANG GQ
  • 作者关键词:   lithium ion batterie, lithium zinc titanate, anode material, cu current collector
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Nanyang Normal Univ
  • 被引频次:   12
  • DOI:   10.1016/j.jpowsour.2016.01.064
  • 出版年:   2016

▎ 摘  要

Lithium zinc titanate (Li2ZnTi3O8) is a desirable anode material for lithium ion batteries (LIBs) due to its low cost, non-toxicity and high safety. However, the low electronic conductivity and not perfect rate capability hinder the commercial application of Li2ZnTi3O8. Here, a facile and effective strategy is developed to fabricate the Li2ZnTi3O8 electrode using the Cu foil with grown graphene and deposited Au nanoparticles as the current collector. The graphene and Au nanoparticles greatly enhance the electrical conductivity of the current collector. The structured Cu current collector has rough interface which can strengthen the adhesion between the Li2ZnTi3O8 active material layer and the current collector, providing an excellent electron transport network and reducing the internal resistance of LIBs. The Li2ZnTi3O8 material supported on the unique structured Cu current collector demonstrates outstanding Li+ storage properties with the reversible capacity of 172.2 mAh g(-1) after 100 cycles at high current density of 4 A g(-1). Even at 6 A g(-1), 148.4 mAh g(-1) can be delivered. The improved rate capability of the structured Li2ZnTi3O8 electrode makes it a promising anode candidate for high performance LIBs. (C) 2016 Elsevier B.V. All rights reserved.