▎ 摘 要
In this study, graphene-oxide (GO)-reinforced Ti-Al-Sn-Zr-Mo-Nb-Si high-temperature titanium-alloy-matrix composites were fabricated by powder metallurgy. The mixed powders with well-dispersed GO sheets were obtained by temperature-controlled solution mixing, in which GO sheets adsorb on the surface of titanium alloy particles. Vacuum deoxygenating was applied to remove the oxygen-containing groups in GO, in order to reduce the introduction of oxygen. The compact composites with refined equiaxed and lamellar alpha phase structures were prepared by hot isostatic pressing (HIP). The results show that in-situ TiC layers form on the surface of GO and GO promotes the precipitation of hexagonal (TiZr)(6)Si(3)particles. The composites exhibit significant improvement in strength and microhardness. The room-temperature tensile strength, yield strength and microhardness of the composite added with 0.3 wt% GO are 9%, 15% and 27% higher than the matrix titanium alloy without GO, respectively, and the tensile strength and yield strength at 600 degrees C are 3% and 21% higher than the matrix alloy. The quantitative analysis indicates that the main strengthening mechanisms are load transfer strengthening, grain refinement and (TiZr)(6)Si(3)second phase strengthening, which accounted for 48%, 30% and 16% of the improvement of room-temperature yield strength, respectively.