• 文献标题:   Influence of processing conditions on microstructural, mechanical and tribological properties of graphene nanoplatelet reinforced UHMWPE
  • 文献类型:   Article
  • 作  者:   MARTINEZMORLANES MJ, PASCUAL FJ, GUERIN G, PUERTOLAS JA
  • 作者关键词:   wear resistance, polymermatrix composite, graphene nanoplatelet, polyethylene, hardnes, particle shape
  • 出版物名称:   JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS
  • ISSN:   1751-6161 EI 1878-0180
  • 通讯作者地址:  
  • 被引频次:   15
  • DOI:   10.1016/j.jmbbm.2020.104248
  • 出版年:   2021

▎ 摘  要

Ultra-high molecular weight polyethylene (UHMWPE) is a relevant thermoplastic in industry and a well-proven standard biomaterial in joint replacements. To enhance its tribological properties while preserving its bulk ones, composite coatings on a UHMWPE substrate were prepared using non-functionalised graphene nanoplatelet (GNP) at reinforcement concentration of 0.1-5 wt% and two mechanical mixing techniques (ball mill or blade mixer) with different consolidation temperatures of 175-240 degrees C. Changes in morphology and size of the UHMWPE particles before hot-pressing were observed in function of the mechanical mixing techniques applied. Wear rate was affected by graphene content, reaching a minimum at 0.5 wt% GNP, with a reduction of 20 and 15%, for ball milling and blade mixer, respectively. However, blade mixer increased the wear rate by around twice respect the ball milling results, for all the studied materials. The coefficient of friction decreased notably, by similar to 25%, below 3 wt% GNP content, and hardness increased by 24%, regardless of the mechanical mixing process used. Finally, consolidation temperature had a positive influence on wear rate at temperatures of around 195 degrees C, which could be related to the free radical scavenger effect of the GNP.