• 文献标题:   Engineering electrical properties of graphene: chemical approaches
  • 文献类型:   Review
  • 作  者:   KIM YJ, KIM Y, NOVOSELOV K, HONG BH
  • 作者关键词:   graphene, doping, bandgap, electrical propertie, chemical method
  • 出版物名称:   2D MATERIALS
  • ISSN:   2053-1583
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   16
  • DOI:   10.1088/2053-1583/2/4/042001
  • 出版年:   2015

▎ 摘  要

To ensure the high performance of graphene-based devices, it is necessary to engineer the electrical properties of graphene with enhanced conductivity, controlled work function, opened or closed bandgaps, etc. This can be performed by various non-covalent chemical approaches, including molecular adsorption, substrate-induced doping, polymerization on graphene, deposition of metallic thin films or nanoparticles, etc. In addition, covalent approaches such as the substitution of carbon atoms with boron or nitrogen and the functionalization with hydrogen or fluorine are useful to tune the bandgaps more efficiently, with better uniformity and stability. In this review, representative examples of chemically engineered graphene and its device applications will be reviewed, and remaining challenges will be discussed.