• 文献标题:   Reduction of Graphene Oxide Using Citrus hystrix Peels Extract for Methylene Blue Adsorption
  • 文献类型:   Article
  • 作  者:   PRILIANA V, SUCITRO C, WIJAYA R, LUNARDI VB, SANTOSO SP, YULIANA M, GUNARTO C, ANGKAWIJAYA AE, IRAWATY W
  • 作者关键词:   reduced graphene oxide, kaffir lime peel, methylene blue, adsorption, green route
  • 出版物名称:   SUSTAINABILITY
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/su141912172
  • 出版年:   2022

▎ 摘  要

Kaffir lime peels extract was used as an agent for the reduction of graphene oxide (GO) into reduced graphene oxide (rGO) via a simple room temperature-dispersion process. The GO obtained from the Hummers process is dispersed in polyphenols rich extract at a varied GO-to-extract ratio of 1:1, 1:2, 1:3, and 1:4. The formation of rGO was confirmed through SEM, FTIR, XPS, XRD, and N-2 sorption characterization. The restoration of C=C group and the reduction of several oxygen-containing groups confirmed the successful formation of rGO from GO. The resultant rGOs were used in the adsorption system for methylene blue uptake. The results indicated that the rGOs prepared at a GO-to-extract ratio of 1:2 had the highest adsorption capacity than rGO at other ratios. The XPS spectrum analysis of rGO 1:2 showed a higher C-C/C-O ratio than the other rGOs, indicating a higher number of adsorption sites which aid in improving the adsorption performance. The adsorption isotherm and kinetic studies were conducted to gain insight into the mechanism and rate of methylene blue uptake by the rGOs. The adsorption isotherm systems were consistent with Langmuir isotherm model with the highest adsorption capacity of 118 mg g(-1) by rGO 1:2. The kinetic adsorption data are well represented by the pseudo-second order model, the adsorption equilibrium was achieved within 400 min with the overall uptake rate of 0.3 mg g(-1) min(-1).