• 文献标题:   Room-temperature synthesis of BiOI/Graphene oxide foam composite for phenol removal under visible light
  • 文献类型:   Article
  • 作  者:   HE RA, LOU ZM, GUI J, TANG B, XU DF
  • 作者关键词:   bismuth oxyiodide, graphene oxide foam, insitu synthesi
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Changsha Univ
  • 被引频次:   2
  • DOI:   10.1016/j.apsusc.2019.144370
  • 出版年:   2020

▎ 摘  要

The coupling of graphene-based materials is a widely adopted method to effectively separate photo-induced electrons and holes, and consequently, improve the performance of photocatalysts. However, the surface modification of semiconductors with graphene materials can block incident light; this is undesirable for the activity enhancement of photocatalysts. To solve this problem, a composite of graphene oxide foam coated with bismuth oxyiodide (GOF-BiOI) was synthesized at room temperature using an in-situ deposition approach. In the composite, BiOI flake arrays stand vertically and uniformly on the surface of GOF. Furthermore, the as-prepared GOF-BiOI exhibited a higher photocatalytic activity than BiOI and GO-modified BiOI for the oxidization of phenol under visible light. Based on a collective analysis of the reactive species, photoluminescence, light absorption, textural and morphological properties, the enhanced photocatalytic activity of GOF-BiOI was attributed to the electron trapping role of GOF, which effectively suppress charge recombination, and to the unique structure of GOF-BiOI, which favored not only light absorption but also the attachment of reactive materials and the surface of BiOI.