• 文献标题:   Dispersion of triethanolamine-functionalized graphene oxide (TEA-GO) in pore solution and its influence on hydration, mechanical behavior of cement composite
  • 文献类型:   Article
  • 作  者:   HU MM, GUO JT, FAN JJ, LI PP, CHEN D
  • 作者关键词:   triethanolamine, graphene oxide, dispersion, mechanical behavior, pore solution, crack propagation
  • 出版物名称:   CONSTRUCTION BUILDING MATERIALS
  • ISSN:   0950-0618 EI 1879-0526
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   10
  • DOI:   10.1016/j.conbuildmat.2019.04.180
  • 出版年:   2019

▎ 摘  要

Re-aggregation of graphene oxide (GO) in cementitious solutions compromises the mechanical enhancement of cement composite. We chemically functionalized GO via triethanolamine (TEA), the removal of -C-O-C- groups on basal planes and the attachment of extra -OH groups on edges promoted its dispersibility during hydration and in cement paste. When incorporated into cement, TEA-GO provides more nucleation sites due to the better dispersion, further promoting the hydration degree. TEA-GO enhanced the compressive strength and flexural strength by 9.4-31% and 8.1-36.7% respectively, which was significantly higher than that of GO(4.1-17.2%; 7.8-20%). (C) 2019 Elsevier Ltd. All rights reserved.