• 文献标题:   Comparison on Properties of Lithium Iron Phosphate/Graphene Composite Prepared by Two Methods
  • 文献类型:   Article
  • 作  者:   HU GR, PENG QY, PENG ZD, GAO YB, DU K
  • 作者关键词:   composite cathode material, lithium iron phosphate, graphene, electrochemical performance
  • 出版物名称:   CHINESE JOURNAL OF INORGANIC CHEMISTRY
  • ISSN:   1001-4861
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   3
  • DOI:  
  • 出版年:   2015

▎ 摘  要

Using FeSO4 center dot 7H(2)O, NH4H2PO4, H2O2, Li2CO3, C6H12O6 and GO as raw materials, LiFePO4/C/G-2 composite cathode material prepared by mixing FePO4 center dot 2H(2)O, Li2CO3 and GO and LiFePO4/C/G-1 by mixing FePO4 center dot 2H(2)O/GO and Li2CO3 were compared. Crystal structure, morphology and electrochemical performance of the two samples were investigated by X-ray diffraction(XRD), scanning electron microscope(SEM), Transmission Electron Microscope (TEM), electrochemical impedance spectroscopy (EIS) test and charge-discharge test. LiFePO4/C/G-1 showed better electrochemical performances compared to LiFePO4/C/G-2. When the chemical synthesis method product (LiFePO4/C/G-1) was charged-discharged in 2.5 similar to 4.1 V, the initial discharge capacity was 158.15 and 150.5 mAh . g(-1) at 0.1C and 1C rate, respectively. After cycling for 500 times at 1C rate, the retention of discharge capacity was 98.3%.