• 文献标题:   Manganese oxide supported partially reduced graphene oxide as a highly active and durable catalyst for the amination of benzene
  • 文献类型:   Article
  • 作  者:   RANA S, VARADWAJ GBB, JONNALAGADDA SB
  • 作者关键词:   manganese oxide, partially reduced graphene oxide, nanocomposite, singlestep conversion, benzene to aniline, single product
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1016/j.catcom.2021.106329 EA JUN 2021
  • 出版年:   2021

▎ 摘  要

We report the preparation by a simple one-pot wet process of nanocomposites of different loading of manganese oxide supported on partially reduced graphene oxide (MnO2/pRGO). The nanocomposites showed excellent catalytic activity for the one-step amination of benzene. The 5 wt% MnO2/pRGO catalyst showed good efficiency towards benzene conversion (77%) with 100% selectivity towards aniline under mild reaction conditions for 90 min at 70 degrees C. From the recycle experiments, a 12% decrease in conversion after the 4th run was found. The new catalytic materials were characterised by XRD, HRTEM, SEM, Raman techniques and N2 physical adsorption measurements.