• 文献标题:   Nanoscale friction and wear of a polymer coated with graphene
  • 文献类型:   Article
  • 作  者:   VACHER R, DE WIJN AS
  • 作者关键词:   friction, graphene, molecular dynamic, polymer
  • 出版物名称:   BEILSTEIN JOURNAL OF NANOTECHNOLOGY
  • ISSN:   2190-4286
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.3762/bjnano.13.4
  • 出版年:   2022

▎ 摘  要

Friction and wear of polymers at the nanoscale is a challenging problem due to the complex viscoelastic properties and structure. Using molecular dynamics simulations, we investigate how a graphene sheet on top of the semicrystalline polymer polyvinyl alcohol affects the friction and wear. Our setup is meant to resemble an AFM experiment with a silicon tip. We have used two different graphene sheets, namely an unstrained, flat sheet, and one that has been crumpled before being deposited on the polymer. The graphene protects the top layer of the polymer from wear and reduces the friction. The unstrained flat graphene is stiffer, and we find that it constrains the polymer chains and reduces the indentation depth.