• 文献标题:   In situ electrodeposition of graphene/nano-palladium on carbon cloth for electrooxidation of methanol in alkaline media
  • 文献类型:   Article
  • 作  者:   SAFAVI A, KAZEMI H, KAZEMI SH
  • 作者关键词:   electrodeposition, graphene nanopalladium composite, carbon cloth, methanol oxidation
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Shiraz Univ
  • 被引频次:   24
  • DOI:   10.1016/j.jpowsour.2013.12.139
  • 出版年:   2014

▎ 摘  要

Electrocatalytic oxidation of methanol in alkaline medium is studied using graphene nano-palladium/carbon cloth (G-Pd/CC). X-ray diffraction, scanning electron microscopy (SEM) and atomic absorption spectrometry are used to characterize G-Pd/CC electrode. Electrochemical characterizations are performed using cyclic voltammetry (CV), chronoamperometry and electrochemical impedance spectroscopy (EIS). The results show that the application of CC as a substrate for G-pd reveals excellent characteristics such as high catalytic activity, stability, tolerance toward poisoning effects for electrooxidation of methanol in alkaline medium. All results show that this electrode is a good candidate for application in direct methanol fuel cells. (C) 2014 Elsevier B.V. All rights reserved.