• 文献标题:   Multiscale porous graphene oxide network with high packing density for asymmetric supercapacitors
  • 文献类型:   Article
  • 作  者:   WAN LM, SUN S, ZHAI T, SAVILOV SV, LUNIN VV, XIA H
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS RESEARCH
  • ISSN:   0884-2914 EI 2044-5326
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1557/jmr.2017.449
  • 出版年:   2018

▎ 摘  要

In this article, we report the synthesis of highly packed graphene oxide-based electrodes (1.25 g/cm(3)) with a three-dimensional multiscale porous structure (denoted as MPGP) through the ZnO nanodisk (100-5(X) nm) template and subsequent H2O2 treatment. Consequently, MPGP with a macropore diameter of 100 nm and a mesopore diameter of 2-3 nm was fabricated as the electrode for supercapacitors (SCs). Significantly, the MPGP achieves a high-volumetric capacitance of 327 F/cm(3) (262 F/g) at a current density of 1 A/g and retains 240 F/cm(3) (192 F/g) at a current density of 16 A/g in 3 M KOH solution. More importantly, it was also capable of delivering a high-volumetric energy density as well as power density in a SC device. Our work shows that the capability of preparing highly packed graphene-based electrodes with high-volumetric as well as specific capacitance is critical for the application of SCs.