• 文献标题:   Superioranticorrosionperformance ofepoxy-basedcomposites withwell-dispersedmelamine modified graphene oxide
  • 文献类型:   Article
  • 作  者:   LI Y, YANG H, WANG FQ, HUANG Y
  • 作者关键词:   application, coating, electrochemistry, graphene, anticorrosion, epoxy
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   0
  • DOI:   10.1002/app.49866 EA SEP 2020
  • 出版年:   2021

▎ 摘  要

In order to improve the dispersion of graphene in epoxy resin, the preparation of melamine modified graphene oxide (M-rGO) is reported. The pi-pi interaction between melamine and graphene oxide (GO) sheet is confirmed via ultraviolet-visible spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy analysis, which endows M-rGO with well dispersion. The dispersion concentration of M-rGO in dimethyl sulfoxide is up to 9 mg/ml, and the stability of which keeps more than 18 months. The anticorrosion performance of M-rGO/epoxy composite coatings was analyzed through electrochemical measurements and salt spray tests, these results indicate that M-rGO has a good barrier effect on corrosive medium and even can replace zinc powder in zinc-rich epoxy. In addition, the reinforced mechanical strength of M-rGO/epoxy composite coatings is proved via mechanical strength tests.