• 文献标题:   Plasmonic Ag nanoparticles anchored ethylenediamine modified TiO2 nanowires@graphene oxide composites for dye-sensitized solar cell
  • 文献类型:   Article
  • 作  者:   KANDASAMY M, SELVARAJ M, KUMARAPPAN C, MURUGESAN S
  • 作者关键词:   dyesensitized solar cell, tio2 nanowire, amine functionalization, plasmonic nanocomposite, photovoltaic performance
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   11
  • DOI:   10.1016/j.jallcom.2022.163743 EA JAN 2022
  • 出版年:   2022

▎ 摘  要

Proficient photoanode is always vital for obtaining high efficiency in dye-sensitized solar cell (DSSC). Herein, ethylenediamine functionalized TiO2 nanowires graphene oxide (TiO2 NW-NH2/GO) has been synthesized and incorporated with Ag nanoparticles. The prepared plasmonic nanocomposites are characterized by various techniques, such as, diffused reflectance, Raman and X-ray photoelectron spectroscopies, X-ray diffraction, and Scanning/transmission electron microscopies (SEM and TEM). The amine functionalized TiO2 NW-NH2/GO/Ag plasmonic nanocomposites exhibit strong light harvesting and better dye loading, leading to high efficiency. The DSSC integrated with TiO2 NW-NH2/GO/Ag nanocomposite photoanode exhibits remarkable photovoltaic performance (short-circuit current density (J(sc)) of 15.09 mA cm(-2) and an overall power conversion efficiency (eta) of 8.76%) which is double that of the DSSC with pure TiO2 NW photoanodes (4.05%). The enhancement of efficiency, mainly due to the increased current density, is attributed to the improved electron transfer at the photoanode/electrolyte interface. Ethylenediamine gives binding interaction between TiO2 and GO/Ag. (C) 2022 Elsevier B.V. All rights reserved.