• 文献标题:   Study on degrading graphene oxide in wastewater under different conditions for developing an efficient and economical degradation method
  • 文献类型:   Article
  • 作  者:   LI T, ZHANG CZ, GU CY
  • 作者关键词:   degradation condition, graphene oxide, mechanism, degradation intermediate, photofenton
  • 出版物名称:   ENVIRONMENTAL TECHNOLOGY
  • ISSN:   0959-3330 EI 1479-487X
  • 通讯作者地址:   Nanjing Univ Informat Sci Technol
  • 被引频次:   1
  • DOI:   10.1080/09593330.2017.1285357
  • 出版年:   2017

▎ 摘  要

With popular application of graphene and graphene oxide (GO), they have been discharged into water. Graphene and GO harm organisms. However, an efficient and economical method for removing graphene and GO in wastewater has seldom been reported. Graphene can be oxidized by hydrogen peroxide to give GO; therefore, degradation of graphene oxide is an important step in the procedure of removal of graphene from water. In this paper, GO degradation via photo-Fenton reaction under different conditions was carried out. Experimental results suggested that GO in wastewater can be efficiently and economically degraded into carbon dioxide and H2O when pH value is 3, concentration of H2O2 and FeCl3 are 35 mM and 5 ppm, respectively. Degradation mechanism of GO was suggested based on UV-vis absorption spectra, scanning electron microscopy, X-ray diffraction and liquid chromatography-mass spectra data of degradation intermediates. This paper suggests an efficient and economical degradation way of GO in wastewater. [GRAPHICS]