• 文献标题:   Multifunctional aminoethylpiperazine-modified graphene oxide with high dispersion stability in polar solvents for mercury ion adsorption
  • 文献类型:   Article
  • 作  者:   JIN JU, YEO H, HAHN JR, YU J, KU BC, YOU NH
  • 作者关键词:   graphene oxide, functionalization, dispersibility, mercury, adsorption
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   Korea Inst Sci Technol KIST
  • 被引频次:   0
  • DOI:   10.1016/j.jiec.2020.07.015
  • 出版年:   2020

▎ 摘  要

Graphene-derived materials including graphene oxide (GO) have infinite potential, but proper dispersibility must be ensured for the utilization of functionalities. To strengthen the compatibility of functionality and dispersibility, a new method by simply functionalizing GO with aminoethylpiperazine (AEP) is provided. Characterization of the synthesized AEP-GO was comprehensively carried out by several spectroscopic methods. Also, as intended, AEP-GO possessed good dispersibility in common organic solvents owing to the characteristics of the polytrophic amines in AEP. In particular, we investigated the possibility of its use as adsorbent for mercury ion as a representative of heavy metals. The solution with AEP-GO of 0.1 wt% achieved Hg2+ removal efficiency of 97.7% at low Hg2+ concentration of 50 ppm. Also, among the various adsorbent concentration, maximum adsorption capacity and removal efficiency were 107.2 mg/g and 98.4%, respectively. In this regard, our findings contribute to the discovery of new approaches to preparing graphene materials. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.