• 文献标题:   Transparent, High-Thermal-Conductivity Ultradrawn Polyethylene/Graphene Nanocomposite Films
  • 文献类型:   Article
  • 作  者:   PAN XL, SHEN LH, SCHENNING APHJ, BASTIAANSEN CWM
  • 作者关键词:   graphene, polyethylene, thermal conductivity, transparency, ultradrawn composite
  • 出版物名称:   ADVANCED MATERIALS
  • ISSN:   0935-9648 EI 1521-4095
  • 通讯作者地址:   Eindhoven Univ Technol
  • 被引频次:   14
  • DOI:   10.1002/adma.201904348
  • 出版年:   2019

▎ 摘  要

Transparent, ultradrawn, ultrahigh molecular weight polyethylene (UHMWPE)/graphene nanocomposite films with a high thermal conductivity are successfully fabricated by solution-casting and solid-state drawing. It is found that the low optical transmittance (<75%) of the ultradrawn UHMWPE/graphene composite films is drastically improved (>90%) by adding 2-(2H-benzontriazol-2-yl)-4,6-ditertpentylphenol (BZT) as a second additive. This high transmission is interpreted in terms of a reduced void content in the composite films and the improved dispersion of graphene both of which decrease light scattering. The high thermal conductivity is attributed to the pi-pi interaction between BZT and graphene. In addition, a high specific thermal conductivity of approximate to 75 W m(-1) K-1 rho(-1) of the ultradrawn UHMWPE/graphene/BZT composite films is obtained, which is higher than most metals and polymer nanocomposite. These transparent films are potentially excellent candidates for thermal management in various applications due to a combination of low density, ease of processing, and high thermal conductivity.