• 文献标题:   Pseudocapacitive performance of phenothiazine functionalized graphene aerogel
  • 文献类型:   Article
  • 作  者:   LEE SP, ALI GAM, ASSIRI MA, KONG KV, TEO EYL, CHONG KF
  • 作者关键词:   graphene aerogel, phenothiazine, functionalization, pseudocapacitive, supercapacitor
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.apsusc.2022.156069 EA DEC 2022
  • 出版年:   2023

▎ 摘  要

This study utilizes light adsorbing molecule, phenothiazine (PTZ) to reduce graphene oxide (GO) and func-tionalize into PTZ-rGO aerogel (PTZ-rGO). The UV excited PTZ reduces GO via electron transfer while PTZ is simultaneously oxidized and functionalized onto rGO to produce PTZ-rGO aerogel. The optimum incorporation of PTZ on rGO sheets renders good electrochemical active surface area of 495.71 m2 g-1 and enhances the diffusion behavior up to 41.92%. This pseudocapacitive effect and the excellent surface property provide promising charge storage results of 235.5 F g-1 at 0.5 A g-1. Furthermore, the stable charge-discharge cycles with 92% capacitance retention after 10,000 cycles render it an excellent electrode material for supercapacitor fabrication.