• 文献标题:   Synthesis of reduced graphene oxide/NiO nanocomposites for the removal of Cr(VI) from aqueous water by adsorption
  • 文献类型:   Article
  • 作  者:   ZHANG KX, LI HY, XU XJ, YU HW
  • 作者关键词:   cr vi removal, rgo/nio nanocomposite, adsorption, langmuir, mechanism
  • 出版物名称:   MICROPOROUS MESOPOROUS MATERIALS
  • ISSN:   1387-1811 EI 1873-3093
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   24
  • DOI:   10.1016/j.micromeso.2017.07.037
  • 出版年:   2018

▎ 摘  要

In this work, we report a room-temperature approach to synthesizing reduced graphene oxidei/NiO (RGO/NiO) nanocomposites. The chemical structure of RGO/NiO nanocomposites were investigated by Transmission Electron Microscope (TEM), X-ray photoelectron spectroscopy (XPS), and X-ray power diffraction (XRD). It is shown by the experiment that the RGO/NiO nanocomposites have strong capacity to absorb the hexavalent chromium ion (Cr (VI)), the maximum adsorption capacity of Cr (VI) on RGO/NiO nanocomposites at pH = 4 and T = 25 degrees C can reach 198 mg g(-1), higher than any other currently reported. The adsorption kinetic data were well described by a pseudo-second-order model. Both Freundlich and Langmuir isotherm models were applied to the experimental data analysis, and the latter proved to be a better fit. The pH value markedly affected the adsorption behavior of RGO/NiO nano composites, but the effect of temperature was insignificant. The probable mechanism of synergistic adsorption of Cr (VI) ions was considered. These results suggest that RGO/NiO nanocomposites have the potential to be applied in industrial wastewater treatment. (C) 2017 Elsevier Inc. All rights reserved.