• 文献标题:   One-step synthesis of palladium-gold-silver ternary nanoparticles supported on reduced graphene oxide for the electrooxidation of methanol and ethanol
  • 文献类型:   Article
  • 作  者:   ZHANG L, WANG H, LI XC, XIA FL, LIU Y, XU XY, GAO JP, XING FB
  • 作者关键词:  
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   24
  • DOI:   10.1016/j.electacta.2014.11.152
  • 出版年:   2015

▎ 摘  要

Simultaneous redox reactions between K2PdCl4, HAuCl4, AgNO3, and graphene oxide (GO) are used to prepare Pd-Au-Ag nanoparticles (NPs) supported on reduced graphene oxide (RGO) by a facile method. The GO serves as the reducing agent, the stabilizing agent and the support. The morphology and composition of the Pd-Au-Ag(1: 1: 1)/RGO NPs are characterized by transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, thermo-gravimetric analysis, Raman spectroscopy and electrochemical measurements. The prepared Pd-Au-Ag(1: 1: 1)/RGO has good electrocatalytic activity and stability for the oxidation of methanol and ethanol in alkaline media. This prepared Pd-Au-Ag(1: 1: 1)/RGO catalyst should have great potential for use in direct alcohol fuel cell. (C) 2014 Elsevier Ltd. All rights reserved.