• 文献标题:   One-step amine modification of graphene oxide to get a green trifunctional metal-free catalyst
  • 文献类型:   Article
  • 作  者:   YANG AW, LI JJ, ZHANG C, ZHANG WQ, MA N
  • 作者关键词:   graphene oxide, diethylenetriamine, modification, trifunctional catalyst, recyclability
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   33
  • DOI:   10.1016/j.apsusc.2015.04.033
  • 出版年:   2015

▎ 摘  要

Graphene oxide is modified by diethylenetriamine through a one-step route to prepare GO-NH(CH2)(2)NH(CH2)(2)NH2 (GO-DETA), which has primary and secondary amino groups and carboxyl groups. GO-DETA is characterized by Fourier transform-infrared spectrum (FT-IR), X-ray diffraction spectroscopy (XRD), thermo-gravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The catalytic performance of obtained GO-DETA is investigated in Knoevenagel condensation and Michael addition in water; the results show it can be used as an efficient and stable catalyst. In addition, it has other features, such as simple preparation, good recyclability and environmental friendliness. (C) 2015 Elsevier B.V. All rights reserved.