• 文献标题:   Simple synthesis of chitosan/alginate/graphene oxide/UiO-67 amphoteric aerogels: Characterization, adsorption mechanism and application for removal of cationic and anionic dyes from complex dye media
  • 文献类型:   Article
  • 作  者:   JING ZY, LI YH, ZHANG Y, CHEN KW, SUN YH, WANG MZ, CHEN B, ZHAO SY, JIN YH, DU QJ, PI XX, WANG YQ
  • 作者关键词:   amphoteric aerogel, complex dyes wastewater, adsorption
  • 出版物名称:   INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
  • ISSN:   0141-8130 EI 1879-0003
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ijbiomac.2023.124683 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

A chitosan/alginate/graphene oxide/UiO-67 (CS/SA/GO/UiO-67) amphoteric aerogel was synthesized success-fully. A series of characterization experiments of CS/SA/GO/UiO-67 amphoteric aerogel was performed by SEM, EDS, FT-IR, TGA, XRD, BET, and zeta potential. The competitive adsorption properties of different adsorbents for complex dyes wastewater (MB and CR) at room temperature (298 K) were compared. Langmuir isotherm model predicted that the maximum adsorption quantity of CS/SA/GO/UiO-67 for CR and MB was 1091.61 and 1313.95 mg/g, respectively. The optimum pH values of CS/SA/GO/UiO-67 for the adsorption of CR and MB were 5 and 10, respectively. The kinetic analysis showed that the adsorption of MB and CR on CS/SA/GO/UiO-67 was more suitable for the pseudo-second-order and pseudo-first-order kinetic model, respectively. The isotherm study revealed that the adsorption of MB and CR was consistent with the Langmuir isotherm model. The thermody-namic study demonstrated that the adsorption process of MB and CR was exothermic and spontaneous. FT-IR analysis and zeta potential characterization experiments revealed that the adsorption mechanism of MB and CR on CS/SA/GO/UiO-67 depended on 7C -7C bond, hydrogen bond, and electrostatic attraction. Repeatable ex-periments showed that the removal rates of MB and CR of CS/SA/GO/UiO-67 after six cycles of adsorption were 67.19 and 60.82 %, respectively.