• 文献标题:   Rapid and Effective Functionalization of Graphene Oxide by Ionic Liquid
  • 文献类型:   Article
  • 作  者:   YAN WB, HUANG Y, XU YF, HUANG L, CHEN YS
  • 作者关键词:   graphene oxide, ionic liquid, functionalization, ionic interaction, conductivity
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Nankai Univ
  • 被引频次:   17
  • DOI:   10.1166/jnn.2012.5755
  • 出版年:   2012

▎ 摘  要

Functionalized graphene oxide (DDIB-GO) sheets, which can be homogeneously distributed into ortho-dichlorobenene, were obtained via rapid and effective covalent functionalization with imidazolium ionic liquids (1,3-didodecylimidazolium bromine) through ion exchange. The resulting DDIB-GO sheets were characterized by Fourier transform infrared spectroscopy (FTIR), UV Vis NIR spectroscopy, X-ray photoelectron spectroscopy (XPS), thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), Atomic force microscopy (AFM). Furthermore, FTIR, XPS and TGA show that the 1,3-didodecylimidazolium have been covalently attached to the GO sheets. UV Vis NIR, TEM, and AFM demonstrate that after functionalization, the size and shape of DDIB-GO sheets had little change compared with GO sheets and it was mostly dispersed in single layer. And good electronic conductivity of the film prepared from DDIB-GO in ODCB was obtained after high temperature annealing.