• 文献标题:   Synergistic effect of trimetallic-based CuxMox/Co1_xO nanoparticles/reduced graphene oxide as high efficient electrocatalyst for oxygen evolution reaction
  • 文献类型:   Article
  • 作  者:   NIYITANGA T, KIM H
  • 作者关键词:   oxygen evolution reaction, electrocatalyst, cobalt oxide, reduced graphene oxide
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.cej.2022.138649 EA AUG 2022
  • 出版年:   2023

▎ 摘  要

The development of an efficient electrocatalyst for the oxygen evolution reaction (OER) is urgently required for sustainable renewable energy production. Owing to the increase in chemical complexity, multimetallic catalysts provide the flexibility to alter their electronic structure to attain superior intrinsic catalytic activity via synergistic effects. In this study, trimetallic CuxMox/Co1_xO nanoparticles grown on reduced graphene oxide (RGO) as a catalyst for the OER were fabricated via a facile solution-hydrothermal synthesis assisted by a calcination process. In the fabricated CuxMox/Co1_xO NPs@RGO hybrid catalyst, the RGO sheet acted as a conductive network to promote electron transfer, thus increasing the electrocatalytic activity. Meanwhile, additional active sites as bridged sites from the Cu and Mo dopants improved the catalytic activity, resulting in outstanding electrochemical activity for the OER. The optimized Cu0.19Mo0.19/Co0.62O NPs@RGO catalyst exhibited a low overpotential of 250 mV and a small Tafel slope of 61 mV/dec at a current density of 10 mA cm(-2) and an overpotential of 550 mV at a high current density of 150 mA cm(-2). This study provides a novel strategy for the development of efficient OER electrocatalysts for large-scale applications.