• 文献标题:   Enhanced charge transportation in a polypyrrole counter electrode via incorporation of reduced graphene oxide sheets for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   GONG F, XU X, ZHOU G, WANG ZS
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   58
  • DOI:   10.1039/c2cp42790g
  • 出版年:   2013

▎ 摘  要

In this work, reduced graphene oxide (RGO) sheets are successfully introduced into the conductive polypyrrole (PPy) matrix as conductive channels and co-catalyst, through simple incorporation of graphene oxide (GO) into PPy and subsequent in situ reduction from GO/PPy to RGO/PPy composite film. The RGO/PPy film is fabricated as a counter electrode for dye-sensitized solar cells, and it exhibits excellent catalytic performance for reduction of triiodide. For this reason, the incorporated RGO sheets significantly improve short-circuit photocurrent density from 14.27 to 15.81 mA cm(-2) and power conversion efficiency from 7.11% to 8.14%, which is comparable with that for the cell based on a Pt cathode.