• 文献标题:   AA-stacked borophene-graphene bilayer as an anode material for alkali-metal ion batteries with a superhigh capacity
  • 文献类型:   Article
  • 作  者:   LIANG YB, LIU Z, WANG J, LIU Y
  • 作者关键词:   alkalimetal ion batterie, borophenegraphene bilayer, adsorption property, diffusion behavior
  • 出版物名称:   CHINESE PHYSICS B
  • ISSN:   1674-1056 EI 2058-3834
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1088/1674-1056/ac7859
  • 出版年:   2022

▎ 摘  要

As the lightest two-dimensional material, monolayer borophene exhibits great potential as electrode materials, but it suffers from stability issues in the free-standing form. Here, the striped-borophene and graphene bilayer (sB/Gr) is found to be a high-performance anode material for rechargeable alkali-metal ion batteries. The first-principles results show that all the three alkali-metal atoms, Li, Na, and K, can be strongly adsorbed on sB/Gr with ultra-low diffusion barriers than that on pristine borophene/graphene, indicating good charge-discharge rates. Remarkably, high storage capacities are proposed for LIBs (1880 mA.h/g), NIBs (1648 mA.h/g), and KIBs (470 mA.h/g) with relatively small lattice change rate (< 2.9%) in the process of alkali-metal atoms intercalations. These intriguing features of sB/Gr make it an excellent choice for batteries.