• 文献标题:   Nitrogen-doped graphene nanosheets with excellent lithium storage properties
  • 文献类型:   Article
  • 作  者:   WANG HB, ZHANG CJ, LIU ZH, WANG L, HAN PX, XU HX, ZHANG KJ, DONG SM, YAO JH, CUI GL
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   484
  • DOI:   10.1039/c1jm00049g
  • 出版年:   2011

▎ 摘  要

In this work, nitrogen-doped graphene nanosheets serving as lithium storage materials are presented. The nitrogen-doped graphene nanosheets were prepared by heat treatment of graphite oxide under an ammonia atmosphere at 800 degrees C for 2 h. Scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy were employed to characterize the prepared product as nitrogen-doped graphene nanosheets with a doping level of ca. 2% nitrogen, where the N binding configuration of the graphene includes 57.4% pyridinic, 35.0% pyrrolic and 7.6% graphitic N atoms. Galvanostatic charge/discharge experiments revealed that these nitrogen-doped graphene nanosheets exhibited a high reversible capacity (900 mA h g(-1) at 42 mA g(-1) (1/20 C)), excellent rate performance (250 mA h g(-1) at a current density of 2.1 A g(-1) (2.5 C)), and significantly enhanced cycling stability, which demonstrated nitrogen-doped graphene nanosheets to be a promising candidate for anode materials in high rate lithium-ion batteries.