▎ 摘　　要

Divalent metal ions (M(2+), M = Cu, Ca or Mg) are used to coordinate oxidized carbon nanotubes (CNTs) and chemically modified graphene (CMG) by the oxygen-containing functional groups. Flexible and transparent conductive films of M(2+)-coordinated CNT/CMG networks are produced by spin coating. The lowest sheet resistance is 680 Omega/sq at 86% transmittance. Chemical doping with SOCl(2) further decreases the value to 370 Omega/sq with only 1% loss in transmittance. The M(2+)-coordinated CNT/CMG films can withstand 200 bending cycles without losing much in sheet resistance. This method provides a new route to transparent electrode materials with high flexibility and strength. (C) 2011 Elsevier Ltd. All rights reserved.