• 文献标题:   Diamine-Alkalized Reduced Graphene Oxide: Immobilization of Sub-2 nm Palladium Nanoparticles and Optimization of Catalytic Activity for Dehydrogenation of Formic Acid
  • 文献类型:   Article
  • 作  者:   SONG FZ, ZHU QL, TSUMORI N, XU Q
  • 作者关键词:   dehydrogenation, formic acid, heterogeneous catalysi, nanoparticle, alkalized reduced graphene oxide
  • 出版物名称:   ACS CATALYSIS
  • ISSN:   2155-5435
  • 通讯作者地址:   Natl Inst Adv Ind Sci Technol
  • 被引频次:   83
  • DOI:   10.1021/acscatal.5b01411
  • 出版年:   2015

▎ 摘  要

An efficient strategy to downsize metal nanoparticles (NPs) and provide basic sites located nearby for optimizing the catalytic performance of reduced graphene oxide (rGO)-supported metal catalysts has been explored, for the first time, by potent alkalization of rGO with diamine. By virtue of the coordination effects between the metal ions and the amine groups ligated to rGO, monodispersed Pd nanoparticles (diameter