• 文献标题:   Excellent performance of flexible supercapacitor based on the ternary composites of reduced graphene oxide/molybdenum disulfide/poly (3,4-ethylenedioxythiophene)
  • 文献类型:   Article
  • 作  者:   CHEN Y, BAI JG, YANG DY, SUN P, LI X
  • 作者关键词:   ternary nanocompo site, porous folded structure, flexible supercapacitor, energy application
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Chengdu Univ Informat Technol
  • 被引频次:   5
  • DOI:   10.1016/j.electacta.2019.135205
  • 出版年:   2020

▎ 摘  要

Rational design of electrode materials and facile synthetic process are essential for developing high performance energy storage devices. Here, a novel reduced graphene oxide/molybdenum disulfide/poly (3,4-ethylenedioxythiophene) ternary material is constructed and deposited on carbon fiber cloth by a facile hydrothermal polymerization method. Thereinto, the graphene oxide is directly used as an oxidant to initiate the polymerization of 3,4-ethylenedioxythiophene. Meanwhile, graphene oxide is transformed into reduced graphene oxide subsequently. This unique ternary flexible electrode exhibits a remarkable areal capacitance of 241.81 mF/cm(2) at a current density of 0.5 mA/cm(2) as well as good stability with 93.7% capacitance retention after 5000 cycles. The excellent electrochemical properties can be attributed to the profitable synergistic effect among three components. Reduced graphene oxide as a framework provides improved electrical conductivity network. Molybdenum disulfide and poly (3,4-ethylenedioxythiophene) afford large pseudocapacitance. Moreover, the ternary electrode possesses porous folded structures which can reinforce the electronic/ionic transport and result in the conspicuous increase in areal capacitance. In addition, the assembled fabric micro-supercapacitor based on the ternary electrodes delivers a superior energy density of 1.44 mu Wh/cm(2) at a power density of 0.058 mw/cm(2). This as-prepared device with excellent flexibility and favorable capacitive performance demonstrates a promising wearable energy storage device. (C) 2019 Elsevier Ltd. All rights reserved.