• 文献标题:   Graphene/SnO2/polypyrrole ternary nanocomposites as supercapacitor electrode materials
  • 文献类型:   Article
  • 作  者:   WANG WJ, HAO QL, LEI W, XIA XF, WANG X
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   123
  • DOI:   10.1039/c2ra21292g
  • 出版年:   2012

▎ 摘  要

A ternary electrode material, based on graphene, tin oxide (SnO2) and polypyrrole (PPy) was obtained via one-pot synthesis. The graphene/SnO2/PPy (GSP) nanocomposite is composed of a thin conducting film of PPy on the surface of graphene/SnO2 (GS). An enhanced specific capacitance (616 F g(-1)) of GSP was obtained at 1 mV s(-1) in 1 M H2SO4 compared with GS (80.2 F g(-1)) and PPy (523 F g(-1)). The GSP electrode shows better cycle stability and no obvious decay after 1000 galvanostatic cycles at 1 A g(-1). Its specific power density and energy density can reach 9973.26 W kg(-1), and 19.4 W h kg(-1), respectively. The excellent electrochemical performance arises from the well-designed structure advantages, the good combination of components and the synergistic effect between the three components. Well-dispersed graphene is used as a framework for sustaining the pseudocapacitive materials of SnO2 and PPy. The PPy film restricts the aggregation and volume change of SnO2 during charge-discharge cycling, and also enhances the surface area. The electrochemical results show that the ternary composite of GSP is a promising candidate electrode material for high-performance supercapacitors.