• 文献标题:   Efficient preparation of cetyltrimethylammonium bromide-graphene oxide composite and its adsorption of Congo red from aqueous solutions
  • 文献类型:   Article
  • 作  者:   SU JZ, HE S, ZHAO ZG, LIU XL, LI H
  • 作者关键词:   ctabgo composite, wastewater treatment, adsorption, congo red
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Southwest Minzu Univ
  • 被引频次:   3
  • DOI:   10.1016/j.colsurfa.2018.06.048
  • 出版年:   2018

▎ 摘  要

Materials based on graphene oxide (GO) have good adsorption capacities to various water contaminants in recent studies, owing to GO can provide more active sites than reduced graphene oxide. However, the inefficient preparation methods and tedious separation steps after adsorption limit their application in wastewater treatment. In this report, a facile method is proposed for the synthesis of a cetyltrimethylammonium bromide (CTAB)-GO composite via ionic interaction. The hydrophobicity of CTAB-GO composite is enhanced by the alkyl chains of CTAB, and thus, it can be readily separated from water-soluble impurities via low-speed centrifugation (3000 rpm for 3 min). The obtained CTAB-GO composite can efficiently remove the azo dye, Congo red from aqueous solutions, with an adsorption capacity as high as 2767 mg/g. Increasing the initial acidity of the solutions enhances the dye removal process. The adsorption kinetic studies reveal that the adsorption equilibrium achieves in similar to 60 min, and the experimental data of the adsorption of Congo red fits well with the pseudo-second-order kinetic model and the Langmuir isotherm. Furthermore, the CTAB-GO composite presents good recycl-ability and the adsorption capacity is greater than 2000 mg/g even at the tenth cycle.