• 文献标题:   Innovative electrochemical sensor based on graphene oxide aerogel wrapped copper centered metal-organic framework to detect catechol
  • 文献类型:   Article
  • 作  者:   XU YQ, YU YJ, XUE S, MA XY, TAO HS
  • 作者关键词:   graphene oxide aerogel, copper centered metalorganic framework, determination, catechol, modified electrode
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   9
  • DOI:   10.1016/j.jelechem.2021.115686 EA SEP 2021
  • 出版年:   2021

▎ 摘  要

An innovative electrochemical sensor was developed based on the modification of a glassy carbon electrode (GCE) surface with graphene oxide aerogel (GA) wrapped copper centered metal-organic framework (Cu-MOF) and was applied to the detection of trace catechol (CT). The morphology, structure of GA/Cu-MOF and electrochemical properties of GA/Cu-MOF/GCE were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and electrochemical techniques, respectively. GA/Cu-MOF/GCE has a wide linear range of 12.5-900 mu mol.L-1 (R-2 = 0.997) and a low limit detection of 1.65 mu mol.L-1. Compared with the unmodified GCE, GA/Cu-MOF/GCE shows better stability, greater sensitivity and higher repeatability. Importantly, this new modified material was successfully prepared and used for the detection of trace amounts of catechol, providing a new idea for electrochemical detection.