• 文献标题:   Probing disorder and charged impurities in graphene by Raman spectroscopy
  • 文献类型:   Article
  • 作  者:   CASIRAGHI C
  • 作者关键词:  
  • 出版物名称:   PHYSICA STATUS SOLIDIRAPID RESEARCH LETTERS
  • ISSN:   1862-6254
  • 通讯作者地址:   Free Univ Berlin
  • 被引频次:   73
  • DOI:   10.1002/pssr.200903135
  • 出版年:   2009

▎ 摘  要

Disorder and doping can strongly affect the properties of graphene. Here we analyze these effects on several samples by Raman spectroscopy. In particular, we show that pristine and unprocessed graphene samples deposited on silicon, covered with a thin silicon oxide layer, show strong variations in their Raman spectra, even in absence of disorder. The variation in the Raman parameters is assigned to charged impurities. This shows that as-deposited graphene is unintentionally doped, reaching charge concentrations up to 10(13) cm(-2) under ambient conditions. The doping varies from sample to sample and the charges are inhomogeneously distributed on a submicron scale. (c) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim