• 文献标题:   A simply effective double-coating cathode with MnO2 nanosheets/graphene as functionalized interlayer for high performance lithium-sulfur batteries
  • 文献类型:   Article
  • 作  者:   SUN W, OU XG, YUE XY, YANG YX, WANG ZH, ROONEY D, SUN KN
  • 作者关键词:   lithium sulfur battery, doublecoating cathode, metallic oxide, graphene
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Beijing Inst Technol
  • 被引频次:   49
  • DOI:   10.1016/j.electacta.2016.04.135
  • 出版年:   2016

▎ 摘  要

Herein, we report a facile and effective adsorption strategy to improve the performance of Lithium-Sulfur (Li-S) batteries. MnO2 nanosheets grown on the surface of highly conductive graphene resulted in a coupled composite bilayer electrode when coated onto a sulfur cathode. In this way, a high initial specific capacity of 1395 mA h g(-1) at a rate of 0.5C, a coulombic efficiency approaching 100% and steady cyclic efficiency with a fade rate of 0.3% per cycle from 10 to 100 cycles has been achieved. This hybrid electrode not only shows enhanced electrochemical performance but can also be easily controlled and scaled thereby aiding future commercialization of high-performance Li-S batteries. (C) 2016 Elsevier Ltd. All rights reserved.