• 文献标题:   Tuning the electronic transport properties of graphene through functionalisation with fluorine
  • 文献类型:   Article
  • 作  者:   WITHERS F, RUSSO S, DUBOIS M, CRACIUN MF
  • 作者关键词:  
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1931-7573 EI 1556-276X
  • 通讯作者地址:   Univ Exeter
  • 被引频次:   76
  • DOI:   10.1186/1556-276X-6-526
  • 出版年:   2011

▎ 摘  要

We demonstrate the possibility to tune the electronic transport properties of graphene mono-layers and multi-layers by functionalisation with fluorine. For mono-layer samples, with increasing the fluorine content, we observe a transition from electronic transport through Mott variable range hopping (VRH) in two dimensions to Efros-Shklovskii VRH. Multi-layer fluorinated graphene with high concentration of fluorine show two-dimensional Mott VRH transport, whereas CF0.28 multi-layer flakes exhibit thermally activated transport through near neighbour hopping. Our experimental findings demonstrate that the ability to control the degree of functionalisation of graphene is instrumental to engineer different electronic properties in graphene materials.