• 文献标题:   One-pot facile route to fabricate the precursor of sulfonated graphene/N-doped mesoporous carbons composites for supercapacitors
  • 文献类型:   Article
  • 作  者:   CHEN P, YANG C, HE Z, GUO KK
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   5
  • DOI:   10.1007/s10853-018-3122-6
  • 出版年:   2019

▎ 摘  要

A facile one-pot aqueous route is firstly proposed to fabricate the precursor of sulfonated graphene/N-doped mesoporous carbons composite (SG/NMC). SG/NMC for supercapacitor applications is subsequently obtained by thermal pyrolysis of this precursor. The obtained SG/NMC possesses the ordered mesostructures with both lattice unit parameter about 14.3nm and much wider distributions of pore sizes, as well as delivers a specific surface area high up to 1039.65m(2)g(-1). Likewise, SG/NMC exhibits a high specific capacitance about 304.2Fg(-1) at 1.0Ag(-1), which is much higher than ordered mesoporous carbons (OMC, 128.9Fg(-1)) and N-doped mesoporous carbons (NMC, 223.3Fg(-1)). Moreover, the resultant carbon displays a capacitance of 209.2Fg(-1) at a current density even up to 50Ag(-1) and the capacity can be retained above 93% after 5000 cycles at 10Ag(-1). The strategy demonstrated here is therefore expected to open up new routes to fabricate graphene and mesoporous carbons composites in aqueous solutions for supercapacitor applications.