• 文献标题:   Hydrogen microexplosion synthesis of platinum nanoparticles/nitrogen doped graphene nanoscrolls as new amperometric glucose biosensor
  • 文献类型:   Article
  • 作  者:   MENG LY, XIA YX, LIU WG, ZHANG L, ZOU P, ZHANG YS
  • 作者关键词:   nitrogen doping, graphene nanoscroll, hydrogen peroxide, glucose, biosensor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Sichuan Agr Univ
  • 被引频次:   38
  • DOI:   10.1016/j.electacta.2014.11.180
  • 出版年:   2015

▎ 摘  要

Platinum nanoparticles/nitrogen doped graphene nanoscrolls (Pt/N-GSS) nanocomposites were prepared by hydrogen microexplosion method. Based on the fantastically scrolled structure, N-doping and high reduction degree properties of N-GSS as catalyst support for Pt nanoparticles, Pt/N-GSS nanocomposites exhibit excellent electrocatalytic activity towards the oxidation of H2O2 with the sensitivity of 25.26 mu A mM(-1) and good linear response from 2 mu M to 16.57 mM. Additionally, taking glucose oxidase (GOD) as the model, the resulting glucose amperometric biosensor not only presents good analytical performance such as a wide linear range (10 mu M-12.55 mM), a high sensitivity (6.36 mu A mM(-1)), but also possesses low detection limit of 1 mu M and long-term stability for detection. (C) 2014 Elsevier Ltd. All rights reserved.