• 文献标题:   Rapid removal of boron from environmental water samples using magnetic graphene oxide: optimized by central composite design
  • 文献类型:   Article
  • 作  者:   ALAFY N, SERESHTI H
  • 作者关键词:   boron, magnetic graphene oxide, inductively coupled plasma optical emission spectroscopy, central composite design, adsorption isotherm model
  • 出版物名称:   DESALINATION WATER TREATMENT
  • ISSN:   1944-3994 EI 1944-3986
  • 通讯作者地址:   Univ Tehran
  • 被引频次:   0
  • DOI:   10.5004/dwt.2019.23948
  • 出版年:   2019

▎ 摘  要

In the present study, magnetic graphene oxide nanocomposite (GO/Fe3O4) was synthesized and used as an efficient adsorbent for the removal of boron from water samples. The removal efficiency was checked using inductively coupled plasma optical emission spectrometry (ICP-OES). The adsorbent was characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and vibrating sample magnetometry (VSM). The effective parameters of adsorption process including pH, adsorbent dosage, and contact time were optimized using a central composite design (CCD). Under the optimal conditions (pH 9.2, adsorbent dose of 82 mg, and contact time of 14.8 min), the relative standard deviation was 1.87% (C= 100 mg L-1, n= 9) with the determination coefficient (R-2) of 0.9980. The maximum adsorption capacity of GO/Fe3O4 was 35.7 mg g(-1). The adsorption isotherm was well fitted with the Langmuir model. Finally, the method was applied to remove boron in tap, mineral and groundwater samples and satisfactory removal efficiencies (95-97%) were obtained.