• 文献标题:   Conductive Graphitic Channel in Graphene Oxide-Based Memristive Devices
  • 文献类型:   Article
  • 作  者:   KIM SK, KIM JY, JANG BC, CHO MS, CHOI SY, LEE JY, JEONG HY
  • 作者关键词:  
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:   Ctr Nanomat Chem React
  • 被引频次:   20
  • DOI:   10.1002/adfm.201602748
  • 出版年:   2016

▎ 摘  要

Electrically insulating graphene oxide with various oxygen-functional groups is a novel material as an active layer in resistive switching memories via reduction process. Although many research groups have reported on graphene oxide-based resistive switching memories, revealing the origin of conducting path in a graphene oxide active layer remains a critical challenge. Here nanoscale conductive graphitic channels within graphene oxide films are reported using a low-voltage spherical-aberration-corrected transmission electron microscopy. Simultaneously, these channels with reduced graphene oxide nanosheets induced by the detachment of oxygen groups are verified by Raman intensity ratio map and conductive atomic force microscopy. It is also clearly revealed that Al metallic protrusions, which are generated in the bottom interface layer, assist the local formation of conductive graphitic channels directly onto graphene oxide films by generating a local strong electric field. This work provides essential information for future carbon-based nanoelectronic devices.