• 文献标题:   Electrodeposition of PdAu Alloy Nanoparticles on Ionic Liquid Functionalized Graphene Film for the Voltammetric Determination of Oxalic Acid
  • 文献类型:   Article
  • 作  者:   SHANG L, ZHAO FQ, ZENG BZ
  • 作者关键词:   pdau nanoparticle, graphene, electrodeposition, oxalic acid, ionic liquid
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   8
  • DOI:   10.1002/elan.201200540
  • 出版年:   2013

▎ 摘  要

An ionic liquid functionalized graphene film was prepared and PdAu nanoparticles (NPs) were electrodeposited on it. The PdAu NPs were characterized by various methods and they showed the features of alloys. In 0.2M H2SO4 solution, oxalic acid (OA) exhibited a sensitive anodic peak at the resulting electrode at about 1.1V (vs. SCE), and the peak current was linear to OA concentration in the range of 5100 mu M with a sensitivity of 45.5 mu A/mM. The detection limit was 2.7 mu M (S/N=3). The electrode was successfully applied to the determination of OA in real sample.