• 文献标题:   Iron(III) porphyrin supported on S and N co-doped graphene quantum dot as an efficient photocatalyst for aerobic oxidation of alcohols under visible light irradiation
  • 文献类型:   Article
  • 作  者:   MAHYARI M, BIDE Y, GAVGANI JN
  • 作者关键词:   graphene quantum dot, photocatalyst, aerobic oxidation, iron iii porphyrin
  • 出版物名称:   APPLIED CATALYSIS AGENERAL
  • ISSN:   0926-860X EI 1873-3875
  • 通讯作者地址:   Malek Ashtar Univ Technol
  • 被引频次:   25
  • DOI:   10.1016/j.apcata.2016.03.010
  • 出版年:   2016

▎ 摘  要

In this study, we report the synthesis and impressive performance of Fe(III)tetra(4-sulfonatophenyl)porphyrins (FeTSPP) supported on S and N co-doped graphene quantum dots (S, N: GQDs) as efficient, recyclable, and noble metal free heterogeneous photocatalyst for the selective aerobic oxidation of alcohols to the corresponding carbonyl compounds. It was found that FeTSPP@S, N: GQDs photocatalyst represents a novel chemical function for efficient visible light catalyzed aerobic alcohol oxidation with good conversions and selectivity in water as a green solvent at room temperature. We envision that FeTSPP@S, N: GQDs provide a promising candidate for the development of highly efficient, recyclable, and industrially applicable photocatalyst in fine chemical production with high activity. (C) 2016 Elsevier B.V. All rights reserved.