• 文献标题:   Engineering a Water-Dispersible, Conducting, Photoreduced Graphene Oxide
  • 文献类型:   Article
  • 作  者:   KONKENA B, VASUDEVAN S
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Indian Inst Sci
  • 被引频次:   11
  • DOI:   10.1021/jp512759w
  • 出版年:   2015

▎ 摘  要

A critical limitation that has hampered widespread application of the electrically conducting reduced graphene oxide (r-GO) is its poor aqueous dispersibility. Here we outline a strategy to obtain water-dispersible conducting r-GO sheets, free of any stabilizing agents, by exploiting the fact that the kinetics of the photoreduction of the insulating GO is heterogeneous. We show that by controlling UV exposure times and pH, we can obtain r-GO sheets with the conducting sp(2)-graphitic domains restored but with the more acidic carboxylic groups, responsible for aqueous dispersibility, intact. The resultant photoreduced r-GO sheets are both conducting and water-dispersible.