• 文献标题:   The microwave-assisted ionic liquid nanocomposite synthesis: platinum nanoparticles on graphene and the application on hydrogenation of styrene
  • 文献类型:   Article
  • 作  者:   LEE JY, YUNG TY, LIU LK
  • 作者关键词:   graphene, pt nanoparticle, ionic liquid, microwave, hydrogenation of styrene
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1931-7573 EI 1556-276X
  • 通讯作者地址:   Natl Cent Univ
  • 被引频次:   10
  • DOI:   10.1186/1556-276X-8-414
  • 出版年:   2013

▎ 摘  要

The microwave-assisted nanocomposite synthesis of metal nanoparticles on graphene or graphite oxide was introduced in this research. With microwave assistance, the Pt nanoparticles on graphene/graphite oxide were successfully produced in the ionic liquid of 2-hydroxyethanaminium formate [HOCH2CH2NH3][HCO2]. On graphene/graphite oxide, the sizes of Pt nanoparticles were about 5 to 30 nm from transmitted electron microscopy (TEM) results. The crystalline Pt structures were examined by X-ray diffraction (XRD). Since hydrogenation of styrene is one of the important well-known chemical reactions, herein, we demonstrated then the catalytic hydrogenation capability of the Pt nanoparticles on graphene/graphite oxide for the nanocomposite to compare with that of the commercial catalysts (Pt/C and Pd/C, 10 wt.% metal catalysts on activated carbon from Strem chemicals, Inc.). The conversions with the Pt nanoparticles on graphene are > 99% from styrene to ethyl benzene at 100A degrees C and under 140 psi H-2 atmosphere. However, ethyl cyclohexane could be found as a side product at 100A degrees C and under 1,520 psi H-2 atmosphere utilizing the same nanocomposite catalyst.