▎ 摘　　要

Reduced graphene oxide (rGO) was used to encapsulate Na3V2(PO4)(2)F-3@Carbon nanoparticles to overcome its inherent low electronic conductivity and achieve superior sodium storage performance. This as-prepared cathode delivers a remarkable rate performance with a discharge capacity of ca. 64 mA h g(-1) at 70C and an ultra-long-term cyclability over 4000 cycles with great capacity retention of 81% at 30C. This excellent performance can be attributed to the favorable combination of fast ionic conductivity of the NASICON structure and the interpenetrating conductive carbon framework; thus bringing a good pseudocapacitive quality to this material. Furthermore, thanks to the good sodium storage properties at low potential, a symmetric full cell can be assembled using Na3V2(PO4)(2)F-3@C@rGO as both cathode and anode. The full cell delivers a high discharge capacity of 53 mA h g (1) at 20C rate, further demonstrating the feasibility of this hybrid material for smart grids.