• 文献标题:   Chemical vapor deposition monolayer graphene functionalization by the Bingel reaction
  • 文献类型:   Article
  • 作  者:   JIN L, LIU TC
  • 作者关键词:   graphene, cvd, cyclopropylation, monolayer
  • 出版物名称:   JOURNAL OF MACROMOLECULAR SCIENCE PART APURE APPLIED CHEMISTRY
  • ISSN:   1060-1325 EI 1520-5738
  • 通讯作者地址:   Xuzhou Coll Ind Technol
  • 被引频次:   2
  • DOI:   10.1080/10601325.2016.1176444
  • 出版年:   2016

▎ 摘  要

Graphene and its derivatives are being studied in nearly all fields of science and engineering. Much effort has been devoted to exploring the fundamental physical and chemical properties of graphene. This paper focuses on the chemical vapor deposition (CVD) monolayer graphene functionalized by the Bingel reaction (Cyclopropylation). From AFM test, the thickness of the sample increased from 0.48 nm to 1.19 nm after reaction for 24 h. According to Raman test, the intensity ratio between D and G peaks (I-D/I-G) increased from 0.01 to nearly 0.1 after reaction for 24. The peak area ratio between C-O and C=C increased from 0.39 to 1.02, the peak area ratio between O-C=O and C=C increased from 0.15 to 0.29 based on XPS results after reaction for 24 h. Therefore, this functionalization reaction for CVD monolayer graphene is successful and can be used in further research for graphene and its derivatives.